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A Level · Cambridge (CIE) · 9701

Explain disposal challenges for poly(alkene)s

Relate slow biological breakdown and harmful combustion products to the difficulty of disposing of poly(alkene)s.

Section 20 · Polymerisation

Addition polymerisation · Cambridge 9701 AS Chemistry · 20.1

AS Level; Cambridge International Chemistry 9701, syllabus for 2028–2030. The taught examples are addition polymers of alkenes; do not generalise their disposal behaviour to every polymer. Written practice is self-checked

Before you begin

  • Recognise C=C bonds and displayed, structural and repeat-unit formulae from Topics 13–14.

Work on paper. Try each question before revealing help, and explain why your method works.

Quick readiness check

Which disposal concern is specifically stated for poly(alkene)s?

What you will learn

  • Recognise that poly(alkene)s are non-biodegradable
  • Explain why this causes disposal difficulty
  • Recognise that combustion may produce harmful products

Persistence makes disposal difficult

Poly(alkene)s such as poly(ethene) and poly(propene) are non-biodegradable in the syllabus context. They do not readily break down through biological processes, so discarded material can persist and accumulate if it is not managed.

Their persistence makes disposal and waste management difficult. Reuse and recycling can reduce some waste, but they depend on sorting, collection and suitable processing; they do not make every discarded item disappear.

Combustion has its own risks

Burning poly(alkene)s can produce harmful combustion products. The syllabus expects recognition of this difficulty, rather than a detailed toxicology list or an assumption that burning is a safe disposal method.

A complete evaluation should connect the polymer property to a consequence and a realistic limitation. Do not claim that all polymers have identical biodegradability or combustion products; this outcome specifically concerns poly(alkene)s.

Pause and explain

Why is combustion not a simple risk-free solution for poly(alkene) waste?

Put the idea to work

Worked example

Give two reasons why disposing of poly(alkene) waste can be difficult.

Show the worked solution
  1. Consider what happens to the material in the environment.
  2. Consider the products if it is burned.
  3. Connect each property to a disposal consequence.

Answer Poly(alkene)s are non-biodegradable, so they can persist and accumulate. Combustion may produce harmful products, so burning is not a risk-free solution.

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From guided practice to a new situation

Write your answer and reasoning first. Use a hint only if you are stuck. The model solution is for self-checking; your written work is not automatically marked.

1 · Guided

Explain how non-biodegradability creates a waste-management problem for poly(ethene).

Give me a hint

Link resistance to biological breakdown with persistence after disposal.

Compare my reasoning
  1. Poly(ethene) is a poly(alkene).
  2. It is non-biodegradable in the syllabus context.
  3. Persistent waste can accumulate if not collected and managed.

Because poly(ethene) is non-biodegradable, it can persist in the environment and accumulate, creating a long-term disposal problem.

Look for these in your work

  • Correct polymer class
  • Property stated
  • Environmental consequence linked
2 · Independent

A proposal is to burn all discarded PVC. Give a syllabus-based reason this is not automatically a safe solution.

Give me a hint

Consider the stated combustion concern, not only the reduction in volume.

Compare my reasoning
  1. Combustion may produce harmful products.
  2. Reducing visible waste does not remove the hazard.
  3. State the limitation without claiming all polymers burn identically.

Burning can produce harmful combustion products, so it is not automatically a safe disposal method. The exact risk depends on the materials and conditions.

Look for these in your work

  • Hazard identified
  • Proposal evaluated
  • Claim appropriately limited
3 · Transfer

Compare recycling and disposal by burning for poly(alkene) waste, giving one limitation of each approach.

Give me a hint

Use the two syllabus difficulties and avoid presenting either option as universally complete.

Compare my reasoning
  1. Recycling depends on collection and sorting.
  2. Burning may produce harmful products.
  3. Relate both to the need for managed disposal.

Recycling can recover material but depends on effective collection, sorting and processing. Burning may reduce waste volume but can produce harmful combustion products. Neither option removes the need for appropriate waste management.

Look for these in your work

  • Both approaches addressed
  • One limitation each
  • Balanced conclusion

Common mistakes

  • Calling all plastics biodegradable
  • Treating burning as harmless
  • Naming recycling without explaining its limitations
  • Claiming every polymer has the same disposal behaviour
Recall without your notes

What can you explain now?

Which disposal concern is specifically stated for poly(alkene)s?

Compare with the explanation

They are non-biodegradable

Their persistence makes disposal difficult.

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Make it stick

Which two syllabus properties make poly(alkene) disposal difficult, and what consequence follows from each?

If you needed the solution, close it and solve the problem again from a blank page. A correct answer is stronger when you can explain the reason for each step.

Keep learning Chemistry

Course scope and assessment

Four hundred and forty-two original lessons map the published learning outcomes across AS Chemistry Topics 1–22 and A Level Topics 23–37, with guided, independent and transfer practice and explained answers. Every numbered subject-content topic and listed outcome tag now has a mapped lesson sequence. Topic 32 maps all 12 hydroxy-compound outcome tags in 11 lessons; Topic 33 maps all 15 carboxylic-acid and derivative outcome tags in 16 lessons; Topic 34 maps all 22 nitrogen-compound outcome tags in 20 lessons; Topic 35 maps all 12 polymerisation outcome tags in 16 lessons; Topic 36 maps all four organic-synthesis outcome tags in 14 lessons; Topic 37 maps all 22 chromatography and NMR outcome tags in 18 lessons. Cambridge's 2028–2030 Version 1 syllabus states that there are no significant changes which affect teaching from the preceding edition; the routes are aligned to that edition. This is 37 of the 37 numbered subject-content topics. Full cumulative exam assessment, Paper 3 laboratory competence, Paper 5 investigation practice and human subject-teacher review remain outstanding. Written practice is self-checked and does not certify exam readiness.

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