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IGCSE · Cambridge (CIE) · 0625

Describe a liquid specific heat capacity experiment

Use liquid mass by difference, a representative temperature and a container energy correction.

Specific heat capacity pathway · 2.2.2

Extended only (Supplement); Physics 0625, 2026–2028, section 2.2.2. These lessons explain average particle kinetic energy, calculate specific heat capacity and describe solid/liquid methods. Written calculations and method analysis are self-checked

Before you begin

  • Use c = ΔE/(mΔθ) and IVt.
  • Distinguish sample mass from container-plus-sample mass.

Work on paper. Try each question before revealing help, and explain why your method works.

Quick readiness check

An empty vessel is 0.080 kg and the filled vessel 0.280 kg. What mass belongs to the liquid?

What you will learn

  • Describe an insulated-liquid method using sample mass and mixed temperature.
  • Calculate an apparent estimate and a supplied container/loss correction.
An original liquid method separates filled mass from empty-vessel mass: 0.280 − 0.080 = 0.200 kg. A schematic insulated vessel has an immersed heater, a thermometer and suitable mixing; openings in the cover are not a sealed pressure vessel. For supplied 4320 J input, 5 K rise, container heat capacity 60 J/K and surroundings loss 220 J, liquid gain is 3800 J. The diagram is method analysis, not construction instructions or a performed experiment.Liquid mass by difference0.280 − 0.080 = 0.200 kgHeaterProbeMixRepresentative liquid temperatureContainer gain: 60 × 5 = 300 JLiquid gain: 4320 − 300 − 2203800 J in the supplied account
An original liquid method separates filled mass from empty-vessel mass: 0.280 − 0.080 = 0.200 kg. A schematic insulated vessel has an immersed heater, a thermometer and suitable mixing; openings in the cover are not a sealed pressure vessel. For supplied 4320 J input, 5 K rise, container heat capacity 60 J/K and surroundings loss 220 J, liquid gain is 3800 J. The diagram is method analysis, not construction instructions or a performed experiment.

Determine the liquid sample and its temperature

Weigh the empty container and then container plus liquid; subtract to find liquid mass. In a teacher-supervised method, use a suitable insulated vessel, appropriately rated immersed heater, thermometer and an appropriate cover with openings for the apparatus. Follow the laboratory procedure for the heater's immersion and electrical safety; the vessel is not sealed to build pressure.

Record initial temperature and heater voltage, current and time. Suitable controlled stirring or mixing gives a more representative liquid temperature rather than one hot region near the heater. Keep the heater appropriately immersed throughout the approved run and record the final mixed temperature. A drawing and paper plan are not evidence of practical competence.

Include the container in the account

For 12 V, 2.0 A and 180 s, input is 4320 J. If liquid mass is 0.20 kg and its rise is 5.0 K, assigning all input to the liquid gives apparent c = 4320 J/(kg K). The container and other apparatus may also warm, and energy can reach the surroundings. A value resembling a familiar material does not prove the assumptions correct.

If a supplied container heat capacity is 60 J/K, its gain for a 5.0 K rise is 300 J. With a further stated surroundings loss of 220 J and no other destinations in this model, liquid gain is 4320 − 300 − 220 = 3800 J, giving c = 3800 J/(kg K). This is a corrected result for the supplied account, not a measured universal material value. Container heat capacity in J/K differs from liquid specific heat capacity in J/(kg K).

Pause and explain

Container heat capacity is 60 J/K and its rise 5.0 K. What energy does it gain?

Put the idea to work

Worked example

Empty container mass is 0.080 kg; filled mass is 0.280 kg. Input is 4320 J, rise 5.0 K, container heat capacity 60 J/K and supplied loss 220 J. Find corrected liquid c.

Show the worked solution
  1. Liquid mass is 0.280 − 0.080 = 0.200 kg.
  2. Container gain is 60 × 5.0 = 300 J; liquid gain is 4320 − 300 − 220 = 3800 J.
  3. c = 3800/(0.200 × 5.0) = 3800 J/(kg K).

Answer 3800 J/(kg K) for the supplied corrected model.

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From guided practice to a new situation

Write your answer and reasoning first. Use a hint only if you are stuck. The model solution is for self-checking; your written work is not automatically marked.

1 · Guided

Describe the liquid method's mass and temperature measurements and the purpose of insulation and mixing.

Give me a hint

Identify the sample and obtain a representative temperature interval.

Compare my reasoning
  1. Find liquid mass by filled minus empty vessel mass.
  2. Use the approved insulated setup and suitable mixing to record initial/final liquid temperatures.
  3. Measure heater voltage, current and time, then evaluate container heating and transfer out.

A liquid-only mass, representative interval and explicit energy account.

Look for these in your work

  • Separate liquid from container.
  • Explain mixing and insulation without claiming perfection.
2 · Independent

For 12 V, 2.0 A, 180 s, liquid mass 0.20 kg and rise 5.0 K, find the all-input apparent c.

Give me a hint

Do not apply corrections that have not been supplied.

Compare my reasoning
  1. IVt = 4320 J.
  2. mΔθ = 0.20 × 5.0 = 1.0 kg K.
  3. Apparent c = 4320/1.0 = 4320 J/(kg K).

Apparent c = 4320 J/(kg K).

Look for these in your work

  • Calculate input consistently.
  • Label the all-input assumption.
3 · Transfer

Correct the same 4320 J input using container heat capacity 60 J/K, rise 5.0 K, and surroundings loss 220 J. Assume no other destinations.

Give me a hint

Subtract container gain and the stated loss before dividing.

Compare my reasoning
  1. Container gain is 300 J.
  2. Liquid gain is 4320 − 300 − 220 = 3800 J.
  3. c = 3800/(0.20 × 5.0) = 3800 J/(kg K).

3800 J/(kg K) under the supplied corrected account.

Look for these in your work

  • Use the container's heat-capacity units.
  • Keep the no-other-destinations condition explicit.

Common mistakes

  • Use liquid mass by difference, not gross filled mass.
  • Container heat capacity and liquid specific heat capacity have different units.
  • Mixing and insulation improve a method without guaranteeing perfect uniformity or zero losses.
Recall without your notes

What can you explain now?

Why use suitable mixing during the liquid method?

Compare with the explanation

To obtain a more representative sample temperature.

Local liquid near the heater may be hotter than the rest; an unmixed local reading can misrepresent the sample.

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Make it stick

Describe liquid mass by difference, representative temperature and the distinction between apparent and corrected specific heat capacity.

If you needed the solution, close it and solve the problem again from a blank page. A correct answer is stronger when you can explain the reason for each step.

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Course scope and assessment

491 sequenced Physics lessons provide 1473 guided, independent and application problems. 58 of 58 syllabus sections have full linked teaching sequences; 0 sections remain pending. Three earlier starter overviews remain available but are not counted as full sequences. The map covers all six subject areas for 2026–2028 and keeps review and assessment limits visible. This is available content, not full programme completion, an exam grade or certified mastery. Written practice is self-checked. Supervised practical experience, cumulative assessment and human subject-teacher review remain pending. Paper method exercises do not demonstrate practical competence or complete either practical-assessment route.

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