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IGCSE · Cambridge (CIE) · 0625

State water's melting and boiling reference temperatures

Use 0°C and 100°C with their pure-water and standard-atmospheric-pressure conditions.

Changes of state pathway · 2.2.3

Core and Extended; Physics 0625, 2026–2028, section 2.2.3. Explain energy input during melting/boiling, water's standard-pressure temperatures, condensation/solidification, surface evaporation and liquid cooling. Detailed boiling/evaporation comparisons, rate factors and cooling a contacted object belong to the labelled Supplement lessons. Written practice is self-checked

Before you begin

  • Distinguish melting from boiling and evaporation.
  • Read Celsius temperatures and a heating curve.

Work on paper. Try each question before revealing help, and explain why your method works.

Quick readiness check

What are the school reference values for pure water at standard atmospheric pressure?

What you will learn

  • Know water's melting and boiling temperatures at standard atmospheric pressure.
  • Recognise pressure, composition and process conditions before interpreting a reading.
An original qualitative pure-water heating curve at standard atmospheric pressure separates solid warming, melting at 0°C, liquid warming, boiling at 100°C and gas warming. Horizontal position is schematic heating progress, not calibrated elapsed time or energy; plateau widths cannot compare latent-energy amounts or durations. Temperature positions use y = 430 − 2.5θ in drawing units. Continued input changes state during the plateaus; actual observations need appropriate pressure, composition and measurement conditions.Pure water · standard atmospheric pTemperature / °C0100MeltingBoilingHeating progress · schematicEnergy enters on both plateausWidths are not time or energy scalesTemperature can stay constant
An original qualitative pure-water heating curve at standard atmospheric pressure separates solid warming, melting at 0°C, liquid warming, boiling at 100°C and gas warming. Horizontal position is schematic heating progress, not calibrated elapsed time or energy; plateau widths cannot compare latent-energy amounts or durations. Temperature positions use y = 430 − 2.5θ in drawing units. Continued input changes state during the plateaus; actual observations need appropriate pressure, composition and measurement conditions.

Remember values with conditions

For pure water at standard atmospheric pressure, the school reference melting temperature is 0°C and the boiling temperature is 100°C. The melting value refers to the solid/liquid transition, while the boiling value refers to liquid/gas boiling. Say the pressure condition with the values; a different pressure can change the boiling temperature.

The 0°C value is not absolute zero. Liquid water can exist between the reference transitions, and it can evaporate below 100°C. Knowing that a sample is at 20°C does not exclude surface evaporation. A temperature label alone also does not show that all the sample has finished a transition or is a single phase.

Observations need more than one number

A mixture or dissolved substances can change transition behaviour, so the pure-water values are not a universal rule for every liquid labelled water-containing. For a supplied pure-water standard-pressure model, apply the listed values; for an unspecified situation, avoid certifying an exact transition from one reading without composition and pressure information.

Vapour is gaseous water and is not itself a visible white cloud. Visible mist consists of small liquid droplets formed when vapour condenses. Bubbles observed before sustained boiling can also include dissolved gas, so 'any bubble proves boiling at exactly 100°C' is too strong. The question must provide enough process and pressure evidence.

Pause and explain

Does 100°C have to be the boiling temperature for water at every pressure?

Put the idea to work

Worked example

State the school reference melting and boiling temperatures of pure water at standard atmospheric pressure.

Show the worked solution
  1. Identify the solid-to-liquid reference.
  2. Identify the liquid-to-gas boiling reference.
  3. Retain the specified purity and pressure conditions.

Answer Melting: 0°C; boiling: 100°C, at standard atmospheric pressure.

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From guided practice to a new situation

Write your answer and reasoning first. Use a hint only if you are stuck. The model solution is for self-checking; your written work is not automatically marked.

1 · Guided

Give water's reference melting and boiling temperatures and the required pressure condition.

Give me a hint

Attach the pressure condition to both named transitions.

Compare my reasoning
  1. For the school pure-water reference, melting is at 0°C.
  2. Boiling is at 100°C.
  3. These values use standard atmospheric pressure.

0°C melting and 100°C boiling at standard atmospheric pressure.

Look for these in your work

  • Name both processes.
  • Retain the conditions.
2 · Independent

A bowl of pure water is at 20°C and standard atmospheric pressure. Must surface evaporation be absent because it is below 100°C?

Give me a hint

Distinguish evaporation from reaching the boiling point.

Compare my reasoning
  1. 20°C is below the boiling reference.
  2. Surface particles can still escape from the liquid.
  3. The reading does not rule out evaporation.

No; evaporation can occur at 20°C.

Look for these in your work

  • Use the correct process.
  • Avoid treating boiling temperature as an evaporation threshold.
3 · Transfer

A sample contains dissolved material and is at an unspecified pressure. Can its exact boiling temperature be certified as 100°C from the label 'water' alone?

Give me a hint

The reference requires composition and pressure conditions.

Compare my reasoning
  1. 100°C is the pure-water standard-pressure reference.
  2. Composition and pressure in this case do not match confirmed conditions.
  3. An exact boiling temperature needs further evidence.

No; the necessary reference conditions are not established.

Look for these in your work

  • State the missing conditions.
  • Avoid an unsupported exact value.

Common mistakes

  • Retain standard atmospheric pressure.
  • 0°C is not absolute zero.
  • Evaporation can occur below the boiling point.
Recall without your notes

What can you explain now?

Can water evaporate at 20°C?

Compare with the explanation

Yes.

Surface evaporation does not require the liquid to reach its boiling temperature.

After trying it yourself, choose your next review. This is your self-assessment.

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Make it stick

Recall the values with conditions and explain why surface evaporation and visible mist are different evidence.

If you needed the solution, close it and solve the problem again from a blank page. A correct answer is stronger when you can explain the reason for each step.

Keep learning Physics

Course scope and assessment

491 sequenced Physics lessons provide 1473 guided, independent and application problems. 58 of 58 syllabus sections have full linked teaching sequences; 0 sections remain pending. Three earlier starter overviews remain available but are not counted as full sequences. The map covers all six subject areas for 2026–2028 and keeps review and assessment limits visible. This is available content, not full programme completion, an exam grade or certified mastery. Written practice is self-checked. Supervised practical experience, cumulative assessment and human subject-teacher review remain pending. Paper method exercises do not demonstrate practical competence or complete either practical-assessment route.

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