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A Level · Cambridge (CIE) · 9701

Name common acids and alkalis with Brønsted–Lowry theory

Recognise the syllabus's common acids and alkalis and describe proton donation and acceptance.

Equilibria and acids and bases · Cambridge 9701 AS Chemistry · 7.2

AS Level; Cambridge International Chemistry 9701, 2025–2027 syllabus. Equilibrium constants apply at a fixed temperature; include only gaseous or aqueous species in the relevant expressions. For acid–base work, distinguish strength from concentration. Written practice is self-checked

Before you begin

  • Balance equations, interpret reversible arrows and use concentration in mol dm⁻³.

Work on paper. Try each question before revealing help, and explain why your method works.

Quick readiness check

What does a Brønsted–Lowry acid do?

What you will learn

  • State the named acid and alkali formulas
  • Define Brønsted–Lowry acids and bases
  • Identify conjugate acid–base pairs in equations

Learn the limited syllabus list

Common acids: hydrochloric acid HCl, sulfuric acid H₂SO₄, nitric acid HNO₃ and ethanoic acid CH₃COOH. Common alkalis: sodium hydroxide NaOH, potassium hydroxide KOH and ammonia NH₃.

An alkali is a base that produces OH⁻ ions in aqueous solution. Some alkalis contain OH⁻ directly; ammonia reacts with water to produce NH₄⁺ and OH⁻.

Acids donate protons; bases accept them

A Brønsted–Lowry acid is a proton donor. A Brønsted–Lowry base is a proton acceptor. Proton transfer creates a conjugate acid–base pair: after donating H⁺, the acid becomes its conjugate base; after accepting H⁺, the base becomes its conjugate acid.

Water can act as either acid or base depending on its reaction partner. Track H⁺ transfer rather than relying only on whether the formula contains an H or OH group.

Pause and explain

Which is a common acid in the syllabus list?

Put the idea to work

Worked example

In HCl + H₂O → H₃O⁺ + Cl⁻, identify the acid, base and conjugate pair.

Show the worked solution
  1. HCl donates H⁺ to water.
  2. HCl is the acid and H₂O is the base.
  3. Cl⁻ is the conjugate base; H₃O⁺ is the conjugate acid.

Answer HCl is the Brønsted acid, H₂O is the base, and the conjugate pairs are HCl/Cl⁻ and H₂O/H₃O⁺.

Try a topic test

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From guided practice to a new situation

Write your answer and reasoning first. Use a hint only if you are stuck. The model solution is for self-checking; your written work is not automatically marked.

1 · Guided

List the four common acids and three common alkalis specified in this syllabus topic.

Give me a hint

Separate the two lists and include formulae.

Compare my reasoning
  1. Acids: HCl, H₂SO₄, HNO₃, CH₃COOH.
  2. Alkalis: NaOH, KOH, NH₃.
  3. Attach the correct names to the formulas.

Acids: hydrochloric acid HCl, sulfuric acid H₂SO₄, nitric acid HNO₃ and ethanoic acid CH₃COOH. Alkalis: sodium hydroxide NaOH, potassium hydroxide KOH and ammonia NH₃.

Look for these in your work

  • All four acids
  • All three alkalis
  • Names matched to formulas
2 · Independent

For NH₃ + H₂O ⇌ NH₄⁺ + OH⁻, identify the Brønsted acid and base.

Give me a hint

Follow the proton from donor to acceptor.

Compare my reasoning
  1. Water donates H⁺ and becomes OH⁻.
  2. NH₃ accepts H⁺ and becomes NH₄⁺.
  3. Thus water is acid and ammonia is base.

H₂O is the Brønsted acid; NH₃ is the Brønsted base. Their conjugates are OH⁻ and NH₄⁺.

Look for these in your work

  • Proton donor identified
  • Proton acceptor identified
  • Conjugates matched
3 · Transfer

Explain how H₂SO₄ and HSO₄⁻ can be a conjugate acid–base pair.

Give me a hint

A conjugate pair differs by one proton.

Compare my reasoning
  1. H₂SO₄ can donate H⁺.
  2. After donation, the species is HSO₄⁻.
  3. The pair differs by one proton.

H₂SO₄ is the acid and HSO₄⁻ its conjugate base; they differ by one H⁺.

Look for these in your work

  • Proton transfer stated
  • Conjugate role correct
  • One-proton difference identified

Common mistakes

  • Defining a Brønsted acid as an OH⁻ donor
  • Calling proton acceptance oxidation
  • Forgetting ammonia acts as an alkali in water
  • Mismatching a species with its conjugate partner
Recall without your notes

What can you explain now?

What does a Brønsted–Lowry acid do?

Compare with the explanation

Donates a proton

An acid is a proton donor.

After trying it yourself, choose your next review. This is your self-assessment.

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Make it stick

How do you identify a Brønsted acid, base and their conjugates from a reaction equation?

If you needed the solution, close it and solve the problem again from a blank page. A correct answer is stronger when you can explain the reason for each step.

Keep learning Chemistry

Course scope and assessment

Four hundred and forty-two original lessons map the published learning outcomes across AS Chemistry Topics 1–22 and A Level Topics 23–37, with guided, independent and transfer practice and explained answers. Every numbered subject-content topic and listed outcome tag now has a mapped lesson sequence. Topic 32 maps all 12 hydroxy-compound outcome tags in 11 lessons; Topic 33 maps all 15 carboxylic-acid and derivative outcome tags in 16 lessons; Topic 34 maps all 22 nitrogen-compound outcome tags in 20 lessons; Topic 35 maps all 12 polymerisation outcome tags in 16 lessons; Topic 36 maps all four organic-synthesis outcome tags in 14 lessons; Topic 37 maps all 22 chromatography and NMR outcome tags in 18 lessons. Cambridge's 2028–2030 Version 1 syllabus states that there are no significant changes which affect teaching from the preceding edition; the routes are aligned to that edition. This is 37 of the 37 numbered subject-content topics. Full cumulative exam assessment, Paper 3 laboratory competence, Paper 5 investigation practice and human subject-teacher review remain outstanding. Written practice is self-checked and does not certify exam readiness.

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